Drift of particles caused by fluctuations of their sizes


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Abstract

Externally stimulated fluctuations of the size of a particle in an asymmetric environment result in its directional motion. This is demonstrated by considering the particle drift in a periodic symmetric channel, which arises due to fluctuations of the particle size. The emergence of the drift is caused by the time variation of the particle entropy, whereas fluctuations of the diffusion coefficient accompanying fluctuations of the size enhance the drift. The effect of the geometry of the channel and the amplitude and frequency of fluctuations on the drift velocity is studied by the Brownian dynamics method. A coarse-grained analytical description of the process is proposed whose predictions are in satisfactory agreement with the results of simulation.

About the authors

V. Yu. Zitserman

Joint Institute for High Temperatures

Author for correspondence.
Email: vz1941@mail.ru
Russian Federation, Moscow, 125412

Yu. A. Makhnovskii

Topchiev Institute of Petrochemical Synthesis; Institute of Atomic and Molecular Sciences

Email: vz1941@mail.ru
Russian Federation, Moscow, 119991; Taipei, 106

L. I. Trakhtenberg

Semenov Institute of Chemical Physics

Email: vz1941@mail.ru
Russian Federation, Moscow, 119991

D.-Y. Yang

Institute of Atomic and Molecular Sciences

Email: vz1941@mail.ru
Taiwan, Province of China, Taipei, 106

S. H. Lin

Institute of Atomic and Molecular Sciences; Department of Applied Chemistry

Email: vz1941@mail.ru
Taiwan, Province of China, Taipei, 106; Hsinchu, 300

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